It is useful because it creates an actual purchasing system. It is not realistic to believe the person who starts the PO will be the one to select the vendor. Realistically, someone is going to request materials/equipment, it is going to be approved by someone, and then another person will shop prices and buy the materials from various vendors. Technically this can be accomplished with WOs but there is not a workflow option for WOs, so you can't control who gives approval. Additionally, you'd need to create multiple POs from one WO rather than just assigning vendors to the line items of the material requesting and automatically creating multiple POs.
This sounds like a useful idea. Do you see the Material Requests entered in the Mobile App, the Browser App or Both. We do have a feature coming that allows material received on site (other than the option in the Daily Log) that may work well with your suggestion.